Nucleotide and Partner-Protein Control of Bacterial Replicative Helicase Structure and Function
2013
Cellular replication forks are powered by ring-shaped, hexameric helicases that encircle and unwind DNA. To better understand the molecular mechanisms and control of these enzymes, we used multiple methods to investigate the bacterial replicative...Read more about Nucleotide and Partner-Protein Control of Bacterial Replicative Helicase Structure and Function
Luminescent Solar Concentration with Semiconductor Nanorods and Transfer-Printed Micro-Silicon Solar Cells
2013
We utilize CdSe/CdS seeded nanorods as a tunable lumophore for luminescent concentration. Transfer-printed, ultrathin crystalline Si solar cells are embedded directly into the luminescent concentrator, allowing the study of luminescent concentrators with an area over 5000 times the area of...Read more about Luminescent Solar Concentration with Semiconductor Nanorods and Transfer-Printed Micro-Silicon Solar Cells
Inorganic Micelles as Efficient and Recyclable Micellar Catalysts
2013
An “inorganic micelle” structure that has a hydrophilic cavity and hydrophobic surface has been synthesized. The inorganic micelles possess large surface area and controllable hydrophobic/hydrophilic interface. It shows high catalytic efficiency and great recyclability in the bromination...Read more about Inorganic Micelles as Efficient and Recyclable Micellar Catalysts
Design of a Metal–Organic Framework with Enhanced Back Bonding for Separation of N2 and CH4
2013
Gas separations with porous materials are economically important and provide a unique challenge to fundamental materials design, as adsorbent properties can be altered to achieve selective gas adsorption. Metal–organic frameworks represent a rapidly expanding new class of porous adsorbents...Read more about Design of a Metal–Organic Framework with Enhanced Back Bonding for Separation of N2 and CH4
Cobalt Particle Size Effects in the Fischer-Tropsch Synthesis and in the Hydrogenation of CO2 Studied with Nanoparticle Model Catalysts on Silica
2013
We have investigated the effect of cobalt nanoparticle size in Fischer–Tropsch synthesis (CO/H2) and have compared it to data obtained for carbon dioxide hydrogenation (CO2/H2) using model catalysts produced by...Read more about Cobalt Particle Size Effects in the Fischer-Tropsch Synthesis and in the Hydrogenation of CO2 Studied with Nanoparticle Model Catalysts on Silica
Enhanced Solid-Sate Order and Field-Effect Hole Mobility through Control of Nanoscale Polymer Aggregation
2013
Efficient charge carrier transport in organic field-effect transistors (OFETs) often requires thin films that display long-range order and close π–π packing that is oriented in-plane with the substrate. Although some polymers have achieved high field-effect mobility with such solid-state...Read more about Enhanced Solid-Sate Order and Field-Effect Hole Mobility through Control of Nanoscale Polymer Aggregation
Pseudo-Rephasing and Pseudo-Free-Induction-Decay Mechanism in Two-Color Three-Pulse Photon Echo of a Binary System
2013
We investigate the two-color three-pulse photon echo peak shift in a (left–right) binary system, where each component consists of a heterodimer. On the basis of the model, we find that the effect of the excitonic asymmetry between two components leads to an additional factor in the peak...Read more about Pseudo-Rephasing and Pseudo-Free-Induction-Decay Mechanism in Two-Color Three-Pulse Photon Echo of a Binary System
Crystalline Fibers of Metal-Peptide Double Ladders
2013
Despite remarkable progress in the field of MOFs, structures based on long-flexible organic linkers are scarce and the majority of such materials rely on rigid linkers. In this work, crystals of a new metal–organic double ladder (MODL) are obtained by linking a pentapeptide (NH...Read more about Crystalline Fibers of Metal-Peptide Double Ladders
Electrodeposited Cobalt-Sulfide Catalyst for Electrochemical and Photoelectrochemical Hydrogen Generation from Water
2013
A cobalt-sulfide (Co–S) film prepared via electrochemical deposition on conductive substrates is shown to behave as an efficient and robust catalyst for electrochemical and photoelectrochemical hydrogen generation from neutral pH water. Electrochemical experiments demonstrate that the film...Read more about Electrodeposited Cobalt-Sulfide Catalyst for Electrochemical and Photoelectrochemical Hydrogen Generation from Water
Bright Cathodoluminescent Thin Films for Scanning Nano-Optial Excitation and Imaging
2013
Demand for visualizing nanoscale dynamics in biological and advanced materials continues to drive the development of subdiffraction optical probes. While many strategies employ scanning tips for this purpose, we instead exploit a focused electron beam to create scannable nanoscale optical...Read more about Bright Cathodoluminescent Thin Films for Scanning Nano-Optial Excitation and Imaging
The ClpXP Protease Unfolds Substrates using a Constant Rate of Pulling but Different Gears
2013
ATP-dependent proteases are vital to maintain cellular ...Read more about The ClpXP Protease Unfolds Substrates using a Constant Rate of Pulling but Different Gears
Revealing Exciton Dynamics in a Small-Molecule Organic Semiconducting Film with Subdomain Transient Absorption Microscopy
2013
The ultrafast spectroscopy of single domains of polycrystalline films of TIPS-pentacene, a small-molecule organic semiconductor of interest in electronic and photovoltaic applications, is investigated using transient absorption microscopy. Individual domains are distinguished by their...Read more about Revealing Exciton Dynamics in a Small-Molecule Organic Semiconducting Film with Subdomain Transient Absorption Microscopy
Semiconductor Nanowires for Artificial Photosynthesis
2013
In this Perspective, we discuss current challenges in artificial photosynthesis research, with a focus on the benefits of a nanowire morphology. Matching the flux between electrocatalysts and light-absorbers, and between individual semiconducting light-absorbers, are two major issues to...Read more about Semiconductor Nanowires for Artificial Photosynthesis
Vibrational and electronic dynamics of nitrogen–vacancy centres in diamond revealed by two-dimensional ultrafast spectroscopy
2013
The optical and material properties of negatively charged nitrogen–vacancy (NV) centres in diamond make them attractive for applications ranging from quantum information to electromagnetic sensing. These properties are strongly dependent on the vibrational manifold associated with the...Read more about Vibrational and electronic dynamics of nitrogen–vacancy centres in diamond revealed by two-dimensional ultrafast spectroscopy
Complete Dissection of Transcription Elongation Reveals Slow Translocation of RNA Polymerase II in a Linear Ratchet Mechanism
2013
During transcription elongation, RNA polymerase has been assumed to attain equilibrium between pre- and post-translocated states rapidly relative to the subsequent catalysis. Under this assumption, recent single-molecule studies proposed a branched Brownian ratchet mechanism that...Read more about Complete Dissection of Transcription Elongation Reveals Slow Translocation of RNA Polymerase II in a Linear Ratchet Mechanism