Urea-Linked Covalent Organic Frameworks

Abstract: 

2D covalent organic frameworks (COFs) with flexible urea linkages have been synthesized by condensation of 1,3,5-triformylphloroglucinol (TFP) with 1,4-phenylenediurea (BDU) or 1,1′-(3,3′-dimethyl-[1,1′-biphenyl]-4,4′-diyl)diurea (DMBDU). The resulting COF-117 and COF-118 undergo reversible structural dynamics within their layers, in response to inclusion and removal of guest molecules, emanating from urea C—N bond rotation and interlayer hydrogen-bonding interactions. These compounds are the first urea-linked COFs, serving to expand the scope of reticular chemistry.

Author: 
C. Zhao
C. S. Diercks
C. Zhu
N. Hanikel
X. Pei
O. M. Yaghi
Publication date: 
November 15, 2018
Publication type: 
Journal Article