2015 New's Items

Rediscovering Spontaneous Light Emission

February 3, 2015

Berkeley Lab researchers have developed a nano-sized optical antenna that can greatly enhance the spontaneous emission of light from atoms, molecules and semiconductor quantum dots. This advance opens the door to light-emitting diodes (LEDs) that can replace lasers for short-range optical communications, including optical interconnects for microchips, plus a host of other potential applications.

“Since the invention of the laser, spontaneous light emission has been looked down upon in favor of stimulated light emission,” says Eli Yablonovitch, an electrical engineer with Berkeley...

Scientists Set Quantum Speed Limit

January 22, 2015

UC Berkeley, scientists have proved a fundamental relationship between energy and time that sets a “quantum speed limit” on processes ranging from quantum computing and tunneling to optical switching.

The speed limit, that is, the minimal time to transition between two easily distinguishable states, such as the north and south poles representing up and down states of a quantum spin (top), is characterized by a well-known relationship. But the speed limit between two states not entirely distinguishable, which correspond to states of arbitrary latitude and longitude whether on or...

Solving an Organic Semiconductor Mystery

January 16, 2015

Organic semiconductors are prized for light emitting diodes (LEDs), field effect transistors (FETs) and photovoltaic cells. As they can be printed from solution, they provide a highly scalable, cost-effective alternative to silicon-based devices. Uneven performances, however, have been a persistent problem. Scientists have known that the performance issues originate in the domain interfaces within organic semiconductor thin films, but have not known the cause. This mystery now appears to have been solved.

Naomi Ginsberg, a faculty chemist with the U.S. Department of Energy (DOE)’s...

From the Bottom Up: Manipulating Nanoribbons at the Molecular Level

January 12, 2015

Narrow strips of graphene called nanoribbons exhibit extraordinary properties that make them important candidates for future nanoelectronic technologies. A barrier to exploiting them, however, is the difficulty of controlling their shape at the atomic scale, a prerequisite for many possible applications.

Now, researchers at the US Department of Energy’s (DOE) Lawrence Berkeley National Laboratory (Berkeley Lab) and the University of California, Berkeley, have developed a new precision approach for synthesizing graphene nanoribbons from pre-designed molecular building blocks. Using...

From the Lab to Your Digital Device, Quantum Dots Have Made Quantum Leaps

January 8, 2015

Outside his career as a noted nanochemist, Lawrence Berkeley National Laboratory (Berkeley Lab) director Paul Alivisatos is an avid photographer. To show off his photos, his preferred device is a Kindle Fire HDX tablet because “the color display is a whole lot better than other tablets,” he says.

What he may neglect to mention to the viewer is that not only did he take the photograph, he also helped invent the nanotechnology allowing the viewer to see those brilliant greens, rich reds, and bold blues, all while using significantly less energy. In fact, the Kindle display utilizes a...

Strain-Dependent Dynamic Mechanical Properties of Kevlar to Failure: Structural Correlations and Comparisons to Other Polymers

S. N. Raja
S. Basu
A. M. Limaye
T. J. Anderson
C. M. Hyland
L. Lin
A. P. Alivisatos
R. O. Ritchie
2015

The processing of Kevlar to certain strengths by hot-drawing can benefit by quantitative understanding of the correlation between structural and mechanical properties during the pre-drawing process. Here, we use a novel continuous dynamic analysis (CDA) to monitor the evolution in storage modulus and loss factor of Kevlar 49 fibers as a function of strain via a quasi-static tensile test. Unlike traditional dynamic mechanical analysis, CDA allows the tracking of strain-dependent mechanical properties until failure. The obtained dynamic viscoelastic properties of Kevlar 49 are...

Systems Materials Engineering Approach for Solar-to-Chemical Conversion

C. Liu
P. Yang
2015

Solar-to-chemical (STC) production using a fully integrated system is an attractive goal, but to-date there has yet to be a system that can demonstrate the required efficiency or durability, or could be manufactured at a reasonable cost. One can learn a great deal from the natural photosynthesis where the conversion of carbon dioxide and water to carbohydrates is routinely carried out at a highly coordinated system level. There are several key features worth mentioning in these systems: spatial and directional arrangement of the light-harvesting components; charge separation and...

Exciton Dynamics Reveal Aggregates with Intermolecular Order at Hidden Interfaces in Solution-Cast Organic Semiconducting Films

C. Y. Wong
B. L. Cotts
H. Wu
N. S. Ginsberg
2015

Large-scale organic electronics manufacturing requires solution processing. For small-molecule organic semiconductors, solution processing results in crystalline domains with high charge mobility, but the interfaces between these domains impede charge transport, degrading device performance. Although understanding these interfaces is essential to improve device performance, their intermolecular and electronic structure is unknown: they are smaller than the diffraction limit, are hidden from surface probe techniques, and their nanoscale heterogeneity is not typically resolved using X-...