2020 New's Items

Nanodiode-based hot electrons: Influence on surface chemistry and catalytic reactions

Jeong Young-Park
Gabor A. Somorjai
2020

Understanding fundamental mechanisms for surface electronic excitation is of great importance in surface chemistry. Charge transport through metal–oxide interfaces plays a significant role in heterogeneous catalysis. Over the last several decades, a number of experimental and theoretical results suggest that this charge flow through metal–support interfaces leads to catalytic enhancement often observed in mixed catalysts. Direct measurement of charge flow on actual catalysts is a rather challenging task because it requires the use of an electronic circuit. This approach has been...

Enhanced and stabilized hydrogen production from methanol by ultrasmall Ni nanoclusters immobilized on defect-rich h-BN nanosheets

Zhuolei Zhang
Ji Su
Ana Sanz Matias
Madeleine Gordon
Yi-Sheng Liu
Jinghua Guo
Chengyu Song
Chaochao Dun
David Prendergast
Gabor A. Somorjai
Jeffrey J. Urban
2020

Employing liquid organic hydrogen carriers (LOHCs) to transport hydrogen to where it can be utilized relies on methods of efficient chemical dehydrogenation to access this fuel. Therefore, developing effective strategies to optimize the catalytic performance of cheap transition metal-based catalysts in terms of activity and stability for dehydrogenation of LOHCs is a critical challenge. Here, we report the design and synthesis of ultrasmall nickel nanoclusters (∼1.5 nm) deposited on defect-rich boron nitride (BN) nanosheet (Ni/BN) catalysts with higher methanol dehydrogenation...

Catalytic Hydrogen Production from Methane: A Review on Recent Progress and Prospect

Lu-ning Chen
Zhiyuan Qi
Shuchen Zhang
Ji Su
Gabor A. Somorjai
2020

Natural gas (Methane) is currently the primary source of catalytic hydrogen production, accounting for three quarters of the annual global dedicated hydrogen production (about 70 M tons). Steam–methane reforming (SMR) is the currently used industrial process for hydrogen production. However, the SMR process suffers with insufficient catalytic activity, low long-term stability, and excessive energy input, mostly due to the handling of large amount of CO2 coproduced. With the demand for anticipated hydrogen production to reach 122.5 M tons in 2024, novel and...

Nonresonant Metasurface for Fast Decoding in Acoustic Communications

X. Jiang
C. Shi
Y. Wang
J. Smalley
J. Cheng
X. Zhang
2020

Acoustic communication is crucial in underwater exploration, where sound is the dominant information carrier, with significantly less loss and scattering than that of electromagnetic waves. However, the capacity of acoustic communication channels is limited due to the intrinsically low speed of sound relative to that of electromagnetic waves and because the attenuation of acoustic waves underwater increases with frequency. Recently, orbital angular momentum (OAM) has emerged as an alternative multiplexing degree of freedom to encode data onto vortex beams for increasing the capacity...

Nonlinear Optics at Excited States of Exciton Polaritons in Two-Dimensional Atomic Crystals

X. Liu
J. Yi
Q. Li
S. Yang
W. Bao
C. Ropp
S. Lan
Y. Wang
X. Zhang
2020

Exciton polaritons (EPs) are partial-light partial-matter quasiparticles in semiconductors demonstrating striking quantum phenomena such as Bose–Einstein condensation and single-photon nonlinearity. In these phenomena, the governing process is the EP relaxation into the ground states upon excitation, where various mechanisms are extensively investigated with thermodynamic limits. However, the relaxation process becomes drastically different and could significantly advance the understanding of EP dynamics for these quantum phenomena, when excited states of EPs are involved. Here, for...

Unidirectional Extraordinary Sound Transmission with Mode-Selective Resonant Materials

J. Zhu
X. Zhu
X. Yin
Y. Wang
X. Wang
2020

Unidirectional wave propagation can introduce strong direction-dependent energy responses, and thus, greatly benefits the construction of switching and logic devices. Such an effect has drawn much attention in acoustics, but has not been able to practically address the essential issue of insufficient transmission efficiency in the forward direction. Here, we present a one-way structure that experimentally realizes near-total forward acoustic wave transportation, while still maintaining a broadband high contrast ratio and single-mode property. The experimentally observed rectification...

Enhanced ferroelectricity in ultrathin films grown directly on silicon

S. S. Cheema
D. Kwon
N. Shanker
R. d. Reis
S.-L. Hsu
J. Xiao
H. Zhang
R. Wagner
A. Datar
M. R. McCarter
C. R. Serrao
A. K. Yadav
G. Karbasian
C.-H. Hsu
A. J. Tan
L.-C. Wang
V. Thakare
X. Zhang
A. Mehta
E. Karapetrova
R. V. Chopdekar
P. Shafer
E. Arenholz
C. Hu
R. Proksch
R. Ramesh
J. Ciston
S. Salahuddin
2020

Ultrathin ferroelectric materials could potentially enable low-power logic and nonvolatile memories1,...

Ten years of spasers and plasmonic nanolasers

S. I. Azzam
A. V. Kildishev
R.-M. Ma
C.-Z. Ning
R. Oulton
V. M. Shalaev
M. I. Stockman
J.-L. Xu
X. Zhang
2020

Ten years ago, three teams experimentally demonstrated the first spasers, or plasmonic nanolasers, after the spaser concept was first proposed theoretically in 2003. An overview of the significant progress achieved over the last 10 years is presented here, together with the original context of and motivations for this research. After a general introduction, we first summarize the fundamental properties of spasers and discuss the major motivations that led to the first demonstrations of spasers and nanolasers. This is followed by an overview of crucial technological progress,...

Berry curvature memory through electrically driven stacking transitions

J. Xiao
Y. Wang
H. Wang
C. D. Pemmaraju
S. Wang
P. Muscher
E. J. Sie
C. M. Nyby
T. P. Devereaux
X. Qian
X. Zhang
A. M. Lindenberg
2020

In two-dimensional layered quantum materials, the stacking order of the layers determines both the crystalline symmetry and electronic properties such as the Berry curvature, topology and electron correlation1,...

A Thermal Radiation Modulation Platform by Emissivity Engineering with Graded Metal–Insulator Transition

K. Tang
X. Wang
K. Dong
Y. Li
J. Li
B. Sun
X. Zhang
C. Dames
C. Qiu
J. Yao
J. Wu
2020

Thermal radiation from a black body increases with the fourth power of absolute temperature (T4), an effect known as the Stefan–Boltzmann law. Typical materials radiate heat at a portion of this limit, where the portion, called integrated emissivity (εint), is insensitive to temperature (|dεint/dT| ≈ 10−4 °C–1). The resultant radiance bound by the T4 law limits the ability to regulate radiative heat. Here, an unusual...