2024 New's Items

Distinguishing Surface and Bulk Reactivity: Concentration-Dependent Kinetics of Iodide Oxidation by Ozone in Microdroplets

Prophet AM
Polley K
Brown EK
Limmer DT
Wilson KR
2024

Iodine oxidation reactions play an important role in environmental, biological, and industrial contexts. The multiphase reaction between aqueous iodide and ozone is of particular interest due to its prevalence in the marine atmosphere and unique reactivity at the air–water interface. Here, we explore the concentration dependence of the I + O3 reaction in levitated microdroplets under both acidic and basic conditions. To interpret the experimental kinetics, molecular simulations are used to benchmark a kinetic model, which enables insight into the reactivity of...

Three-dimensional dispersion in the type-II Dirac semimetals PtTe2 and PdTe2 revealed through circular dichroism in angle-resolved photoemission spectroscopy

Pelayo I
Bergner D
Williams AJ
Qi J
Zhu P
Nabi M
Huey WLB
Moreschini L
Deng Z
Hadsell T
Denlinger J
Lanzara A
Lu YM
Windl W. Goldberger J
Ojeda-Aristizabal C
2024

PtTe2 and PdTe2 are among the first transition metal dichalcogenides that were predicted to host type-II Dirac fermions, exotic particles prohibited in free space. These materials are layered and air stable, which makes them top candidates for technological applications that take advantage of their anisotropic magnetotransport properties. Here, we provide a detailed characterization of the electronic structure of PtTe2 and PdTe2 using angle-resolved photoemission spectroscopy (ARPES) and density functional theory calculations, offering an alternative interpretation for one of the Dirac-...

Establishing coherent momentum-space electronic states in locally ordered materials

Ciocys ST
Marsal Q
Corbae P
Varjas D
Kennedy E
Scott M
Hellman F
Grushin A
Lanzara A
2024

Rich momentum-dependent electronic structure naturally arises in solids with long-range crystalline symmetry. Reliable and scalable quantum technologies rely on materials that are either not perfect crystals or non-crystalline, breaking translational symmetry. This poses the fundamental questions of whether coherent momentum-dependent electronic states can arise without long-range order, and how they can be characterized. Here we investigate Bi2Se3, which exists in crystalline, nanocrystalline, and amorphous forms, allowing direct comparisons between varying...

Doping dependence of spin-momentum locking in bismuth-based high-temperature cuprate superconductors

2024

Non-zero spin orbit coupling has been reported in several unconventional superconductors due to the absence of inversion symmetry breaking. This contrasts with cuprate superconductors, where such interaction has been neglected for a long time. The recent report of a non-trivial spin orbit coupling in overdoped Bi2212 cuprate superconductor, has re-opened an old debate on both the source and role of such interaction and its evolution throughout the superconducting dome. Using high-resolution spin- and angle-resolved photoemission spectroscopy, we reveal a momentum-dependent spin...

Ultrafast creation of a light-induced semimetallic state in strongly excited 1T-TiSe2

Huber M
Lin Y
Marini G
Moreschini L
Jozwiak C
Bostwick A
Calandra M
Lanzara A
2024
Screening, a ubiquitous phenomenon associated with the shielding of electric fields by surrounding charges, has been widely adopted as a means to modify a material’s properties. While most studies have relied on static changes of screening through doping or gating thus far, here we demonstrate that screening can also drive the onset of distinct quantum states on the ultrafast timescale. By using time- and angle-resolved photoemission spectroscopy, we show that intense optical excitation can drive 1T-TiSe2, a prototypical charge density wave material, almost instantly from a...

Unusually Strong Near-Infrared Photoluminescence of Highly Transparent Bulk InSe Flakes

2024

Bulk γ-InSe has a direct bandgap of 1.24 eV, which corresponds to near infrared wavelengths (λ = 1.0 µm) useful in optoelectronic applications from biometric detectors to silicon photonics. However, its potential for optoelectronic applications is largely untapped due in part to the lack of quantitative studies of its optical properties. Here, the unusually low absorptance and high photoluminescence quantum efficiency of single-crystalline InSe flakes with thickness in the hundreds of nanometers are studied. InSe emits brightly at room temperature from its direct bandgap...

The challenges and promise of sweat sensing

Davis N
Heikenfeld J
Milla C
Javey A
2024

The potential of monitoring biomarkers in sweat for health-related applications has spurred rapid growth in the field of wearable sweat sensors over the past decade. Some of the key challenges have been addressed, including measuring sweat-secretion rate and collecting sufficient sample volumes for real-time, continuous molecular analysis without intense exercise. However, except for assessment of cystic fibrosis and regional nerve function, the ability to accurately measure analytes of interest and their physiological relevance to health metrics remain to be determined. Although sweat is...

Mid-Infrared, Optically Active Black Phosphorus Thin Films on Centimeter Scale

Higashitarumizu N
Kawashima T
Smart T
Yalisove R
Ho CY
Madsen M
Chrzan DC
Scott MC
Jeanloz R
Yusa H
Javey A
2024

Black phosphorus (BP) is a narrow bandgap (∼0.3 eV) semiconductor with a great potential for optoelectronic devices in the mid-infrared wavelength. However, it has been challenging to achieve a high-quality scalable BP thin film. Here we present the successful synthesis of optically active BP films on a centimeter scale. We utilize the pulsed laser deposition of amorphous red phosphorus, another allotrope of phosphorus, followed by a high-pressure treatment at ∼8 GPa to induce a phase conversion into BP crystals. The crystalline quality was improved through thermal annealing, resulting in...

Transient Nanoscopy of Exciton Dynamics in 2D Transition Metal Dichalcogenides

Li J
Yang R
Higashitarumizu N
Dai S
Wu J
Javey A
Grigoropoulos CP
2024

The electronic and optical properties of 2D transition metal dichalcogenides are dominated by strong excitonic resonances. Exciton dynamics plays a critical role in the functionality and performance of many miniaturized 2D optoelectronic devices; however, the measurement of nanoscale excitonic behaviors remains challenging. Here, a near-field transient nanoscopy is reported to probe exciton dynamics beyond the diffraction limit. Exciton recombination and exciton–exciton annihilation processes in monolayer and bilayer MoS2 are studied as the proof-of-concept...

Multicolor Inks of Black Phosphorus for Midwave-Infrared Optoelectronics

Kim JI
Higashitarumizu N
Wang S
Yalisove R
Scott MC
Song SY
Javey A
2024

Black phosphorus (bP) based ink with a bulk bandgap of 0.33 eV (λ = 3.7 µm) has recently been shown to be promising for large-area, high performance mid-wave infrared (MWIR) optoelectronics. However, the development of multicolor bP inks expanding across the MWIR wavelength range has been challenging. Here a multicolor ink process based on bP with spectral emission tuned from 0.28 eV (λ = 4.4 µm) to 0.8 eV (λ = 1.5 µm) is demonstrated. Specifically, through the reduction of bP particle size distribution (i.e., lateral dimension and thickness), the optical bandgap systematically blueshifts...