2024 New's Items

Error mitigated metasurface-based randomized measurement schemes

Ren H
Zhang Y
Zheng Z
Ying C
Xu L
Rahmani M
Whaley KB
2024

Estimating properties of quantum states via randomized measurements has become a significant part of quantum information science. In this paper, we design an innovative approach leveraging metasurfaces to perform randomized measurements on photonic qubits, together with error mitigation techniques that suppress realistic metasurface measurement noise. Through fidelity and purity estimation, we confirm the capability of metasurfaces to implement randomized measurements and the unbiased nature of our error-mitigated estimator. Our findings show the potential of metasurface-based...

Real-time propagation of adaptive sampling selected configuration interaction wave function

Shee A
Huang Z
Head-Gordon M
Whaley KB
2024

We have developed a new time propagation method, time-dependent adaptive sampling configuration interaction (TD-ASCI), to describe the dynamics of a strongly correlated system. We employ the short iterative Lanczos (SIL) method as the time-integrator, which provides a unitary, norm-conserving, and stable long-time propagation scheme. We used the TD-ASCI method to evaluate the time-domain correlation functions of molecular systems. The accuracy of the correlation function was assessed by Fourier transforming (FT) into the frequency domain to compute the dipole-allowed absorption...

Sympathetic Mechanism for Vibrational Condensation Enabled by Polariton Optomechanical Interaction

Shishkov VY
Andrianov ES
Tretiak S
Whaley KB
Zasedatelev AV
2024

We demonstrate a macrocoherent regime in exciton-polariton systems, where nonequilibrium polariton Bose-Einstein condensation coexists with macroscopically occupied vibrational states. Strong exciton-vibration coupling induces an effective optomechanical interaction between cavity polaritons and vibrational degrees of freedom of molecules, leading to vibrational amplification in a resonant blue-detuned configuration. This interaction provides a sympathetic mechanism to achieve vibrational condensation with potential applications in cavity-controlled chemistry, nonlinear, and quantum...

Efficient state preparation for the quantum simulation of molecules in first quantization

Huggins WJ
Leimkuhler O
Stetina TF
Whaley KB
2024

The quantum simulation of real molecules and materials is one of the most highly anticipated applications of quantum computing. Algorithms for simulating electronic structure using a first-quantized plane wave representation are especially promising due to their asymptotic efficiency. However, previous proposals for preparing initial states for these simulation algorithms scale poorly with the size of the basis set. We address this shortcoming by showing how to efficiently map states defined in a Gaussian type orbital basis to a plane wave basis with a scaling that is logarithmic in...

Solving k–SAT problems with generalized quantum measurement

Zhang Y
Lewalle P
Whaley KB
2024

We generalize the projection–based quantum measurement–driven k–SAT algorithm of Benjamin, Zhao, and Fitzsimons (BZF, [1]) to arbitrary strength quantum measurements, including the limit of continuous monitoring. In doing so, we clarify that this algorithm is a particular case of the measurement–driven quantum control strategy elsewhere referred to as “Zeno dragging”. We argue that the algorithm is most efficient with finite time and measurement resources in the continuum limit, where measurements have an infinitesimal strength and duration. Moreover, for solvable k-SAT problems, the...

Reinforcement learning pulses for transmon qubit entangling gates

Nguyen HN
Motzoi F
Metcalf M
Whaley KB
Bukov M
Schmitt M
2024

The utility of a quantum computer is highly dependent on the ability to reliably perform accurate quantum logic operations. For finding optimal control solutions, it is of particular interest to explore model-free approaches, since their quality is not constrained by the limited accuracy of theoretical models for the quantum processor—in contrast to many established gate implementation strategies. In this work, we utilize a continuous control reinforcement learning algorithm to design entangling two-qubit gates for superconducting qubits; specifically, our agent constructs cross-...

Optimal Zeno Dragging for Quantum Control: A Shortcut to Zeno with Action-Based Scheduling Optimization

Lewalle P
Zhang Y
Whaley KB
2024

The quantum Zeno effect asserts that quantum measurements inhibit simultaneous unitary dynamics when the “collapse” events are sufficiently strong and frequent. This applies in the limit of strong continuous measurement or dissipation. It is possible to implement a dissipative control that is known as “Zeno dragging” by dynamically varying the monitored observable, and hence also the eigenstates, which are attractors under Zeno dynamics. This is similar to adiabatic processes, in that the Zeno-dragging fidelity is highest when the rate of eigenstate change is slow compared to the...

Enhancement of vibrationally assisted energy transfer by proximity to exceptional points, probed by fluorescence-detected vibrational spectroscopy

Li ZZ
Whaley KB
2024

Emulation of energy transfer processes in natural systems on quantum platforms can further our understanding of complex dynamics in nature. One notable example is the demonstration of vibrationally assisted energy transfer (VAET) on a trapped-ion quantum emulator, which offers insights for the energetics of light harvesting. In this work, we expand the study of VAET simulation with trapped ions to a non-Hermitian quantum system comprising a -symmetric chromophore dimer weakly coupled to a vibrational mode. We first characterize exceptional points (EPs) and non-Hermitian...

A quantum eigenvalue solver based on tensor networks

Leimkuhler O
Whaley KB
2024

Electronic ground states are of central importance in chemical simulations, but have remained beyond the reach of efficient classical algorithms except in cases of weak electron correlation or one-dimensional spatial geometry. We introduce a hybrid quantum-classical eigenvalue solver that constructs a wavefunction ansatz from a linear combination of matrix product states in rotated orbital bases, enabling the characterization of strongly correlated ground states with arbitrary spatial geometry. The energy is converged via a gradient-free generalized sweep algorithm based on quantum...

Comparing Self-Consistent GW and Vertex-Corrected G0W0 (G0W0Γ) Accuracy for Molecular Ionization Potentials

Wen M
Abraham V
Harsha G
Shee A
Whaley KB
Zgid D
2024

We test the performance of self-consistent GW and several representative implementations of vertex-corrected G0W0 (G0W0Γ). These approaches are tested on benchmark data sets covering full valence spectra (first ionization potentials and some inner valence shell excitations). For small molecules, when comparing against state-of-the-art wave function techniques, our results show that full self-consistency in the GW scheme either systematically outperforms vertex-corrected G...