2021 New's Items

Topology and Symmetry of Quantum Materials via Nonlinear Optical Responses

Orenstein J
Moore JE
Morimoto T
Torchinsky DH
Harter JW
Hsieh D
2021

We review recent progress in the study of photogalvanic effects and optical second-harmonic generation in topological and noncentrosymmetric metals.

Detection of Kardar–Parisi–Zhang hydrodynamics in a quantum Heisenberg spin-1/2 chain

Scheie A
Sherman NE
Dupont M
Nagler SE
Stone MB
Granroth GE
Moore JE
Tennant DA
2021

Classical hydrodynamics is a remarkably versatile description of the coarse-grained behaviour of many-particle systems once local equilibrium has been established1. The form of the hydrodynamical equations is determined primarily by the conserved quantities present in a system. Some quantum spin chains are known to possess, even in the simplest cases, a greatly expanded...

Many-Body Chaos in the Sachdev-Ye-Kitaev Model

Kobrin B
Yang Z
Kahanamoku-Meyer GD
Olund CT
Moore JE
Stanford D
Yao NY
2021

Many-body chaos has emerged as a powerful framework for understanding thermalization in strongly interacting quantum systems. While recent analytic advances have sharpened our intuition for many-body chaos in certain large N theories, it has proven challenging to develop precise numerical tools capable of exploring this phenomenon in generic Hamiltonians. To this end, we utilize massively parallel, matrix-free Krylov subspace methods to calculate dynamical correlators in the Sachdev-Ye-Kitaev model for up...

Enhanced Coherence in Superconducting Circuits via Band Engineering

Chirolli L
Moore JE
2021

In superconducting circuits interrupted by Josephson junctions, the dependence of the energy spectrum on offset charges on different islands is 2e periodic through the Aharonov-Casher effect and resembles a crystal band structure that reflects the symmetries of the Josephson potential. We show that higher-harmonic Josephson elements described by a cos(2φ...

Criticality of Two-Dimensional Disordered Dirac Fermions in the Unitary Class and Universality of the Integer Quantum Hall Transition

Sbierski B
Dresselhaus EJ
Moore JE
Gruzberg IA
2021

Two-dimensional (2D) Dirac fermions are a central paradigm of modern condensed matter physics, describing low-energy excitations in graphene, in certain classes of superconductors, and on surfaces of 3D topological insulators. At zero energy E=0, Dirac fermions with mass m are band insulators, with the Chern number jumping by unity at m...

Nanoscale Disorder Generates Subdiffusive Heat Transport in Self-Assembled Nanocrystal Films

Utterback JK
Sood A
Coropceanu I
Guzelturk B
Talapin DV
Lindenberg AM
Ginsberg NS
2021

Investigating the impact of nanoscale heterogeneity on heat transport requires a spatiotemporal probe of temperature on the length and time scales intrinsic to heat navigating nanoscale defects. Here, we use stroboscopic optical scattering microscopy to visualize nanoscale heat transport in disordered films of gold nanocrystals. We find that heat transport appears subdiffusive at the nanoscale. Finite element simulations show that tortuosity of the heat flow underlies the subdiffusive transport, owing to a distribution of nonconductive voids. Thus, while heat travels diffusively...

‘Eye’ of the molecule—a viewpoint

Lee S
Yaghi OM
2021

If the twentieth century was the age of precisely designed molecules, the twenty-first century is beginning to look like the age of reticulated molecules. In the spirit of the Faraday Discussion meeting, we wish to highlight the power of harnessing the reticulated molecule and suggest that its chemistry can be furthered by viewing our reticular structures from the ‘eye of the molecule’. To clarify what is meant by this term, we wish to first take stock of the current state of reticular chemistry.

Docking of CuI and AgI in Metal–Organic Frameworks for Adsorption and Separation of Xenon

Wang H
Shi Z
Yang J
Sun T
Rungtaweevoranit B
Lyu H
Zhang YB
Yaghi OM
2021

We present a metal docking strategy utilizing the precise spatial arrangement of organic struts as metal chelating sites in a MOF. Pairs of uncoordinated N atoms on adjacent pyrazole dicarboxylate linkers distributed along the rod-shaped Al–O secondary building units in MOF-303 [Al(OH)(C5H2O4N2)] were used to chelate CuI and AgI with atomic precision and yield the metalated Cu- and Ag-MOF-303 compounds [(CuCl)0.50...

From Molecules to Frameworks to Superframework Crystals

Ji Z
Freund R
Diercks CS
Hirschle P
Yaghi OM
Wuttke S
2021

Building chemical structures of complexity and functionality approaching the level of biological systems is an ongoing challenge. A general synthetic strategy is proposed by which progressive levels of complexity are achieved through the building block approach whereby molecularly defined constructs at one level serve as constituent units of the next level, all being linked through strong bonds-"augmented reticular chemistry". Specifically, current knowledge of linking metal complexes and organic molecules into reticular frameworks is applied here to linking the crystals of these...

Vibronic coupling in light-harvesting complex II revisited

Arsenault EA
Schile AJ
Limmer DT
Fleming GR
2021

A growing body of work has pointed to vibronic mixing as a crucial design principle for efficient energy and charge transfer in natural1–3 and artificial systems.4,5 Notable among these studies was the recent observation of vibronically promoted ultrafast energy flow in the major antenna...